cyclocycloalkane

Cyclocycloalkane is a hypothetical or theoretical class of organic compounds that combines features of cycloalkanes and alkynes. The name suggests a structure where a ring of carbon atoms (a cycloalkane) is present, and within that ring, there is at least one carbon-carbon triple bond (an alkyne). However, the formation of a stable triple bond within a ring system is sterically very challenging, especially in smaller rings.

The strain associated with forcing a linear alkyne moiety into a cyclic framework would be significant. For very small rings, such as cyclopentyne or smaller, a true triple bond is generally considered impossible to form without extreme instability. In larger rings, the geometry becomes more accommodating, and it is theoretically possible to have a triple bond. Cyclooctyne is a known example of a cycloalkyne where the strain is manageable. A cyclocycloalkane would, therefore, imply a ring system containing one or more triple bonds, in addition to being a saturated ring structure otherwise.

The synthesis and stability of such compounds would be highly dependent on the ring size and the position of the triple bond. Theoretical studies and computational chemistry can explore the feasibility and properties of hypothetical cyclocycloalkanes. The reactivity would likely be dominated by the characteristic reactions of alkynes, such as addition reactions across the triple bond, but also influenced by the constraints of the cyclic structure. No widely recognized or commonly synthesized examples of compounds specifically termed "cyclocycloalkane" beyond the broader category of cycloalkynes exist in standard organic chemistry literature.