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chargelattice

Chargelattice is a theoretical construct in which electric charges occupy the sites of a fixed lattice and interact through Coulomb-like forces mediated along the lattice. It serves as a discrete model for ionic solids, electrolytes, and certain electronic systems where charge fluctuations are constrained by a lattice geometry.

In a typical formulation, a d-dimensional lattice with N sites hosts charges q_i at each site i.

Variants include the lattice Coulomb gas, where only charges fluctuate and neutral configurations are sampled; and

Applications and relevance include modeling ionic crystals, electrolytes, Wigner crystals in low-density electron systems, and some

Relation to continuum theories: as lattice spacing decreases, the discrete model approaches a continuum Coulomb gas;

The
charges
may
be
restricted
to
integers
or
to
a
finite
set
of
values,
and
the
Hamiltonian
includes
long-range
Coulomb
interactions
typically
written
via
a
lattice
Green's
function,
often
combined
with
short-range
terms.
Neutrality
constraints
(sum_i
q_i
=
0)
are
common.
In
lattice
gauge-theory
language,
Gauss's
law
imposes
a
divergence
constraint
on
the
electric
field,
relating
charges
to
lattice
flux.
Computational
approaches
include
Monte
Carlo
methods
and,
for
continuum
limits,
Ewald
summation
adapted
to
the
lattice.
lattice
dipole
or
spin
models
with
emergent
charge
degrees
of
freedom.
The
charges
may
be
dynamical
(mobile
carriers)
or
frozen
to
represent
ionic
sublattices.
In
two
dimensions,
the
model
connects
to
Kosterlitz-Thouless
physics
and
to
dual
sine-Gordon
descriptions
in
certain
limits.
frustrated
magnetic
materials
where
magnetic
charges
obey
similar
lattice
constraints.
The
chargelattice
also
serves
as
a
testbed
for
algorithms
dealing
with
long-range
interactions
on
lattices.
lattice
artifacts
can
affect
phase
behavior
and
critical
phenomena.
See
also
Coulomb
gas,
lattice
gauge
theory,
Wigner
crystal,
Gauss's
law,
Ewald
summation.