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thoriumargon

Thoriumargon is a term used in theoretical discussions to denote a thorium–argon system. It is not known to exist as a stable compound under standard chemical conditions, and there is no experimental evidence for a well-defined thoriumargon material. In speculative chemistry, thoriumargon may refer to either a diatomic molecule ThAr in the gas phase or to a solid-state form in which thorium is incorporated into an argon-rich matrix or cages.

In gas phase, some high-level quantum chemical calculations predict a weakly bound ThAr diatomic molecule with

Formation and detection remain speculative. Proposed approaches include laser ablation of thorium in an argon atmosphere

Potential interest lies in the study of actinide–noble gas chemistry and in benchmarking relativistic quantum calculations

a
small
dissociation
energy
and
a
linear
or
near-linear
geometry.
In
condensed
phases,
thorium
atoms
might
be
trapped
within
an
argon
lattice
to
form
a
thorium-doped
argon
solid
or
a
clathrate-like
compound,
which
would
require
extreme
pressures
or
cryogenic
temperatures
to
be
stable.
or
embedding
thorium
into
a
cryogenic
argon
matrix
followed
by
spectroscopic
interrogation.
Computational
studies
have
explored
possible
electronic
configurations,
including
thorium-centered
5f
and
6d
orbitals
and
the
nature
of
weak
thorium–argon
interactions.
for
weak,
inert
environments.
Applications
remain
hypothetical,
primarily
serving
as
a
testbed
for
modeling
interactions
between
radioactive
elements
and
inert
matrices.
Safety
considerations
reflect
the
radiological
nature
of
thorium
and
the
inertness
of
argon,
which
poses
no
chemical
hazard
but
requires
standard
radiological
controls.
Related
topics
include
thorium,
argon,
noble
gas
chemistry,
and
actinide
chemistry.