resolen

Resolen is not a standard term in chemical nomenclature, and in many sources the concept is referred to by the related terms resole or resol as part of phenol-formaldehyde resin chemistry. When used, resolen commonly denotes a class of resins produced under basic conditions that are capable of self-curing through residual reactive groups.

Chemistry and production: Resole resins form by alkaline condensation of phenol with excess formaldehyde, yielding methylol-phenol intermediates that polymerize into prepolymers with residual hydroxymethyl groups. These resins are typically partially polymerized and possess reactive sites that enable crosslinking. Unlike some alternative phenol-formaldehyde resins, resoles can cure under heat or with acid/hardening catalysts, forming a hardened, thermoset network.

Properties and forms: Resole resins generally exhibit good bonding strength, heat resistance, and solvent resistance once cured. They are often supplied as liquids or low-viscosity prepolymers and can be formulated as solid, solvent-based, or waterborne systems. The exact properties depend on the formaldehyde-to-phenol ratio, degree of prepolymerization, and additives such as curing catalysts.

Applications: The primary use of resole-type resins is as wood adhesives, particularly for plywood and particleboard, where they cure with heat to form strong bonds. They also serve as binders in foundry sands, laminates, and composite materials, and may be used in coatings or encapsulants in certain formulations.

Safety and regulatory notes: Many phenol-formaldehyde resins release formaldehyde during processing and curing, requiring adequate ventilation and exposure controls. Storage, handling, and disposal follow applicable occupational safety regulations.

See also: phenol-formaldehyde resin, resol, novolac resin.