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potentiodynamische

Potentiodynamic polarization is an electrochemical method used to study corrosion behavior and electrode kinetics by sweeping the potential of a working electrode relative to a reference electrode while recording the resulting current. It is commonly performed with a three-electrode cell in a suitable electrolyte.

During a potentiodynamic scan, the potential is varied at a controlled rate, typically starting near the open-circuit

From polarization curves one extracts Ecorr (corrosion potential) and iCorr (corrosion current density) as measures of

Applications include evaluating corrosivity of environments for metals and coatings, assessing passivation behavior, and screening alloys.

Interpreting results requires caution: the measured iCorr depends on scan rate, surface finish, temperature, and electrolyte

Historically, potentiodynamic polarization emerged in the mid-20th century as a practical extension of polarization methods and

potential
and
moving
in
the
anodic
direction;
cathodic
sweeps
are
also
used.
The
resulting
current–potential
curve,
or
polarization
curve,
provides
information
on
kinetic
parameters
and
corrosion
resistance.
corrosion
rate.
The
anodic
branch
may
show
passivation,
and
the
pitting
potential
Epit
indicates
susceptibility
to
localized
corrosion.
Tafel
slopes
can
be
determined
to
quantify
reaction
kinetics.
It
is
widely
used
in
materials
research
and
quality
control.
composition;
dynamic
sweeping
may
not
reflect
long-term
corrosion
under
constant
potential.
High
scan
rates
can
exaggerate
corrosion
currents;
gas
evolution
may
disturb
the
surface.
remains
a
standard
tool
alongside
other
electrochemical
techniques.