Iodoperoxides

Iodoperoxides are a class of chemical compounds that contain an iodine-oxygen bond with a formal oxidation state of +1 for iodine. These are distinct from iodates and periodates, where iodine has higher positive oxidation states. Iodoperoxides are generally unstable and highly reactive species. Their formation is often transient and can occur in various chemical processes, including reactions involving iodine and oxidizing agents. While not as commonly encountered as their peroxy acid or peroxide counterparts, iodoperoxides play a role in certain organic reactions, particularly in the functionalization of organic molecules. Their reactivity stems from the weak iodine-oxygen bond and the electrophilic nature of the iodine atom. Due to their instability, isolating and characterizing pure iodoperoxides can be challenging, and they are often generated and consumed in situ. Research into iodoperoxides continues to explore their potential applications in synthesis and their involvement in atmospheric chemistry.