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Excitations

An excitation is a state in which a system possesses more energy than its ground state. In quantum systems, excitations are quantized and correspond to the absorption of energy that promotes the system to a higher allowed energy level or to a collective mode. Excitations can be created by external perturbations such as photons, particle collisions, thermal energy, or applied fields, and they typically decay back toward the ground state over characteristic lifetimes.

Different systems support different kinds of excitations. In atoms and molecules, electronic excitations involve promoting electrons

Excitations are often described by their energy spectrum E(k) or E, their momentum, and their lifetime. Theoretical

Commonly cited examples include electronic transitions in atoms and semiconductors, phonons in crystals, and excitons in

Lifetime and decay pathways influence device performance, with some excitations persisting as long-lived states or contributing

to
higher
electronic
orbitals;
vibrational
excitations
involve
quantized
vibrational
motion
of
nuclei;
rotational
excitations
involve
rotation
of
molecules.
In
solids,
electrons
can
be
excited
across
energy
bands,
creating
electron-hole
pairs;
quantized
lattice
vibrations
give
phonons;
collective
spin
oscillations
give
magnons;
bound
electron-hole
pairs
are
excitons;
charge-density
oscillations
are
plasmons.
treatments
use
quantum
mechanics
and
many-body
techniques,
including
perturbation
theory,
Green's
functions,
and
various
lattice
or
band-structure
models.
Experimental
probes
include
spectroscopy,
photoemission
(ARPES),
neutron
scattering,
infrared
and
Raman
techniques,
and
inelastic
light
scattering,
which
reveal
excitation
energies
and
dispersions.
semiconductors.
Excitations
play
a
central
role
in
many
technologies,
such
as
lasers,
light-emitting
diodes,
solar
cells,
and
sensors,
by
controlling
how
energy
is
absorbed,
transported,
or
converted.
to
transport
phenomena
like
superconductivity,
metal-insulator
transitions,
or
collective
quantum
phases.