zoncuring

Zoncuring is a materials processing technique in which the curing process of a polymer, resin, or adhesive is carried out in spatially defined zones, producing controlled gradients in cross-link density, mechanical stiffness, or chemical composition. The term is used in several disciplines and there is no single universally accepted definition.

Principles and methods include thermal zoned curing using temperature gradients or localized heating, photoinitiated curing with patterned light or masks to activate different regions, and staged or catalyst-assisted curing where reactive species are confined to specific zones. Diffusion of reactants may also contribute to gradient formation.

Techniques encompass thermal zoned curing with controllable heaters, masked or projected light for photopolymerizable resins, embedded catalysts or microstructured templates that localize reaction, and layerwise or multi-step approaches in additive manufacturing.

Applications span tailored mechanical properties in polymers and composites, soft robotics, biomedical implants with gradient modulus to better match tissue, adhesive systems with spatially varying bonding strength, and protective coatings featuring gradient barrier properties.

Benefits include the ability to create property gradients, reduce residual stresses, improve adhesion between dissimilar materials, and potentially simplify manufacturing by combining steps.

Limitations involve controlling zone sharpness, diffusion across boundaries, measurement and metrology challenges, process complexity, and material compatibility concerns.

Variations exist: some sources label it zoned curing, zone-specific curing, or gradient curing.

See also: curing, polymerization, gradient materials.