rotationalvibrational

Rotationalvibrational, or ro-vibrational, refers to the coupled motion of rotation and vibration in molecules. In most molecules these motions influence each other: as a molecule vibrates, its moment of inertia changes and its rotational energy levels shift, and conversely rotation affects vibrational energy spacings. This coupling is especially important for understanding molecular spectra in the infrared and microwave regions.

The ro-vibrational energy structure is typically described by first treating vibration with a harmonic or anharmonic oscillator model and rotation with a rigid or slightly nonrigid rotor. The total energy for a given vibrational level v can be written, to a good approximation, as E(v,J) ≈ hc[ω_e(v+1/2) + B_v J(J+1) − D_v J^2(J+1)^2], where B_v is the rotational constant for vibrational level v (often B_v ≈ B_e − α_e(v+1/2)) and D_v accounts for centrifugal distortion. This framework captures how ro-vibrational transitions shift with v and J and why different bands appear at characteristic spacings.

In spectroscopy, ro-vibrational transitions follow selection rules that commonly yield P- and R-branch series, corresponding to ΔJ = −1 and ΔJ = +1, respectively. The presence and intensity of lines depend on the change in dipole moment with vibration and on molecular symmetry. While diatomic molecules often exhibit clean P and R branches, polyatomic species produce many closely spaced lines from multiple vibrational modes, creating complex spectra.

Ro-vibrational analysis underpins infrared spectroscopy, atmospheric science, and astrophysics, enabling the determination of molecular constants, temperatures, and abundances. It remains a foundational concept for interpreting how rotation and vibration shape molecular behavior.