resonanceassisted

Resonanceassisted is an adjective used in several scientific disciplines to denote phenomena in which electronic resonance—delocalization of electrons across a conjugated framework—plays a central role in stabilization or facilitation of a process. The term is typically encountered in discussions of how resonance effects interact with structural or energetic factors to influence outcomes in chemistry, physics, and materials science.

In chemistry, resonance-assisted hydrogen bonding (RAHB) is a well-known example. Here, extended delocalization couples with hydrogen bonding so that bond formation is accompanied by increased conjugation. This resonance assistance can strengthen hydrogen bonds, promote planarity, and influence conformational equilibria and reaction outcomes in organic and biological systems. The concept helps explain unusually strong, directional intramolecular interactions in motifs where a developing conjugated system can spread charge.

In physical chemistry and quantum chemistry, resonance-assisted mechanisms describe effects such as resonance-assisted tunneling or resonance-assisted electron transfer, where alignment of electronic, vibrational, or spin states with energy gaps enhances coupling and increases rates or efficiencies. The specifics depend on the system, but the core idea is that resonance can act cooperatively with structure to enable otherwise less favorable pathways.

Usage notes: the term is not a single formal category; it functions as a descriptive modifier bridging resonance theory with specific phenomena. It is typically hyphenated when used before a noun (resonance-assisted hydrogen bonding), though some writers may render it as resonanceassisted in indexing or keyword contexts.

See also: resonance (chemistry), hydrogen bonding, tunneling, electron transfer.