Home

minimumenergy

Minimum energy, or the minimum-energy principle, is a broad idea in physics and applied mathematics describing how systems settle into states that minimize energy under given constraints. In static problems, the equilibrium configuration corresponds to a minimum of the potential energy. For a particle in a conservative force field, equilibrium occurs where the gradient of the potential energy is zero; stability requires the second derivative (the Hessian) to be positive definite. When constraints are present, the method of Lagrange multipliers finds configurations that minimize energy subject to those constraints.

In quantum mechanics, a related idea is the variational principle: the ground state energy is the lowest

For continuous media and field theories, one often minimizes an energy functional with specified boundary conditions.

Thermodynamics notes that energy minimization applies most cleanly at zero temperature, where systems tend toward minimum

possible
expectation
value
of
the
Hamiltonian.
Any
trial
wavefunction
provides
an
upper
bound
to
the
true
ground-state
energy,
and
the
energy
is
minimized
by
optimizing
the
wavefunction.
The
Rayleigh–Ritz
method
extends
this
approach
to
approximate
eigenvalues
using
a
finite
basis
set.
Examples
include
elastic
deformation
energy,
electrostatic
energy,
and
magnetic
energy.
The
stationary
points
of
these
energy
functionals
satisfy
the
Euler–Lagrange
equations,
which
yield
the
governing
equations
for
the
system.
energy
states,
whereas
at
finite
temperature
entropy
effects
compete
with
energy
minimization.
In
practice,
energy
minimization
problems
are
solved
numerically
via
gradient-based
methods,
conjugate
gradient
techniques,
or
more
advanced
variational
and
finite-element
approaches.
The
landscape
can
include
multiple
local
minima,
so
global
optimization
strategies
or
physical
reasoning
are
often
required
to
identify
the
true
minimum-energy
configuration.