chaingrowth

Chaingrowth is a term used in materials science and related fields to describe growth that proceeds by sequential addition of units to the end of an existing linear chain, producing a chain-like, typically unbranched structure. The concept is most commonly encountered in discussions of chain-growth polymerization, where a reactive chain end adds monomer units in sequence to extend the polymer chain. Chaingrowth contrasts with step-growth processes, in which growth occurs through reactions between functional groups distributed across molecules, often leading to more branched or crosslinked products.

In polymer chemistry, chain-growth polymerization includes mechanisms such as free-radical, ionic, and coordination processes. A defining feature is the presence of an active chain end that continuously reacts with monomer to elongate the chain. Termination or chain-transfer reactions can cap growth or transfer activity, impacting the final molecular weight distribution. In the subset of living or controlled chain-growth polymerizations, termination is minimized or suppressed to achieve better control over molecular weight and architecture.

Applications of chaingrowth processes include the production of high-molecular-weight polymers and elastomers with desirable mechanical properties, as well as resins and coatings. In modeling contexts, chain-growth rules are used to simulate growth phenomena in networks, fibers, and crystalline structures where sequential addition along a primary axis governs the development of the material.

Notes: chaingrowth is not always used as a formal named term; it is often employed descriptively to refer to chain-growth mechanisms or sequential growth phenomena across various domains. Related terms include chain-growth polymerization, living polymerization, and step-growth polymerization.