alkanoxides

Alkanoxides are a class of chemical compounds characterized by the presence of an alkoxide functional group. This group consists of an alkyl group bonded to an oxygen atom, which in turn is negatively charged. The general formula for an alkanoxide can be represented as RO-, where R is an alkyl group and O- is the negatively charged oxygen atom.

Alkanoxides are typically formed by the deprotonation of an alcohol using a strong base, such as an alkali metal hydride or an alkali metal. For example, the reaction of ethanol with sodium hydride produces ethoxide and hydrogen gas. These reactions are often carried out in anhydrous conditions to prevent the alkoxide from reacting with water.

Due to the negative charge on the oxygen atom, alkanoxides are strong nucleophiles and strong bases. This makes them useful reagents in organic synthesis. They can participate in various reactions, including nucleophilic substitution, elimination reactions, and aldol condensations. The specific reactivity of an alkanoxide depends on the nature of the alkyl group and the counterion.

The simplest and most common alkanoxides are methoxide (CH3O-) and ethoxide (C2H5O-), derived from methanol and ethanol, respectively. These are often used as sodium or potassium salts. Larger alkanoxides, such as tert-butoxide ((CH3)3CO-), are also widely employed and exhibit distinct steric and electronic properties that influence their reactivity.