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Siloxanebased

Siloxane-based materials are polymers and networks that feature siloxane moieties—Si–O–Si linkages—with organic groups attached to silicon. Commonly described as silicone-based materials, they combine an inorganic-like backbone with organic side chains, yielding properties useful across many applications.

The Si–O–Si backbone imparts high flexibility, thermal stability, and chemical resistance. Substituents on silicon—such as methyl,

Polymers such as polydimethylsiloxane (PDMS) are among the most widely produced siloxanes, valued for clarity, biocompatibility,

Synthesis typically proceeds by hydrolysis and condensation of silicon chlorides or silanols, or via living polymerization

Applications span sealants, adhesives, lubricants, medical devices, cosmetics, electronics, and aerospace. The combination of chemical resistance,

Health and environmental aspects depend on formulation. Siloxanes generally exhibit low acute toxicity, but certain cyclic

phenyl,
or
longer
alkyl
groups—tune
viscosity,
hardness,
hydrophobicity,
and
dielectric
properties.
Siloxane
materials
range
from
liquids
and
soft
elastomers
to
rigid
resins
and
composites.
and
low
surface
energy.
Other
siloxanes
incorporate
varied
substituents
or
are
crosslinked
to
form
elastomeric
seals,
silicone
rubbers,
or
resinous
coatings.
of
siloxane
monomers.
Resulting
materials
can
be
liquids,
gels,
elastomers,
or
networks,
with
processing
controlled
by
crosslink
density,
chain
length,
and
additives.
weather
stability,
and
a
wide
range
of
mechanical
properties
makes
siloxane-based
materials
versatile
across
industries.
siloxanes
have
raised
environmental
and
regulatory
concerns,
influencing
restrictions
in
cosmetics
and
industrial
use.