Molarlitet

Molarlitet is a fictional crystalline material used in theoretical discussions of advanced porous frameworks. It is described as a two-dimensional metal-oxide layered structure interconnected by organic pillars, creating a three-dimensional porous network. The term combines 'molar' with 'litet', reflecting its proposed role in tuning molecular-scale properties through composition control.

In the standard fictional description, Molarlitet exhibits tunable pore sizes, high thermal and chemical stability, a wide band gap, and a high dielectric constant. Depending on synthesis, its surfaces can be functionalized with various groups to modify adsorption, catalysis, or luminescence. Typical pore openings are described as a few to several angstroms, enabling selective gas separation.

Within the fictional framework, Molarlitet is prepared by solvothermal or solid-state methods from metal salts and multi-dentate organic linkers, using high-temperature, inert conditions. Post-synthetic modifications and doping with lanthanide ions produce luminescent variants.

Applications proposed include dielectric layers for microelectronics, gas storage and separation, catalysis, and luminescent sensors. Its hypothetical high surface area and stability are cited as advantages in energy storage and catalysis.

Molarlitet originated in speculative materials science literature in the early 21st century. It has since appeared in educational materials to illustrate design principles for porous frameworks, though no experimental realization has been reported in the real world as of now.

See also: Metal-organic frameworks, covalent organic frameworks, porous crystals.