Azidoimides
Azidoimides are a class of organic compounds that feature both an azide group (-N3) and an imide function within the same molecule. In practice the term usually refers to azido-substituted imides, most commonly N-azidoimides in which the azide is bonded to the imide nitrogen, although other isomeric arrangements are possible depending on the parent imide structure. The imide portion typically derives from a cyclic dicarboximide, which provides rigidity and an electron-withdrawing environment.
Synthesis and occurrence: Azidoimides are prepared by azidation of suitable imide precursors or by transfer of
Reactivity and motifs: The presence of both azide and imide functionalities affords orthogonal reactivity. Azidoimides can
Applications: They are investigated as versatile building blocks in synthetic organic chemistry, with potential use in
Safety: Azide-containing compounds require careful handling due to potential energetic and toxic properties; appropriate safety protocols