siliconIV
Silicon tetraiodide, often referred to as silicon(IV) iodide, has the chemical formula SiI4. It is a volatile, colorless compound that decomposes upon exposure to moist air, producing hydrogen iodide and silicon dioxide. Silicon tetraiodide is synthesized by the direct reaction of silicon with iodine at elevated temperatures, typically around 500 degrees Celsius, in the absence of oxygen and moisture. This reaction can be represented by the equation: Si + 2I2 → SiI4. It is a member of the silicon tetrahalide family, which also includes silicon tetrachloride (SiCl4), silicon tetrabromide (SiBr4), and silicon tetrafluoride (SiF4). These compounds share a similar tetrahedral molecular geometry around the central silicon atom. Silicon tetraiodide is soluble in nonpolar organic solvents such as carbon disulfide. Its primary uses are in research laboratories as a precursor for the synthesis of silicon-containing organic compounds and in the production of high-purity silicon. Due to its reactivity and sensitivity to moisture, it is handled with care under an inert atmosphere.