dihapto

Dihapto is a term used in organic chemistry to describe the way an atom or group of atoms in a molecule can bind to a metal center. Specifically, it refers to a ligand that is attached to a metal through two atoms. This is a type of hapticity, which is a measure of how many atoms in a ligand are bonded to a metal. The prefix "di" indicates two, and "hapto" refers to the binding.

When a ligand exhibits dihapto coordination, it means that two of its atoms are simultaneously involved in bonding with the metal. This can occur in various ways depending on the structure of the ligand. For instance, in some organometallic compounds, a carbon-carbon double bond or a carbon-carbon triple bond can act as a dihapto ligand, with the two carbons of the pi system binding to the metal. Other examples include ligands with adjacent atoms like oxygen or nitrogen that can chelate to a metal center in a dihapto fashion. The electronic and steric properties of the dihapto ligand can significantly influence the reactivity and stability of the resulting metal complex. Understanding dihapto coordination is crucial for designing and synthesizing new organometallic catalysts and materials.