Perhaloalkanes
Perhaloalkanes are a class of organic compounds that are alkanes where all hydrogen atoms have been replaced by halogen atoms. These halogens can be fluorine, chlorine, bromine, or iodine. The general formula for a perhaloalkane derived from an alkane with n carbon atoms is CnHXm, where X represents a halogen atom and m is the total number of halogen atoms, which will be 2n+2 if all hydrogen atoms are replaced. For example, carbon tetrachloride (CCl4) is a perhaloalkane derived from methane. Hexachloroethane (C2Cl6) is derived from ethane. Perhaloalkanes are generally stable compounds due to the strong carbon-halogen bonds. Their physical properties vary depending on the specific halogen and the number of carbon atoms. Many perhaloalkanes are nonpolar and have low boiling points. They are often insoluble in water but soluble in organic solvents. Historically, some perhaloalkanes, like chlorofluorocarbons (CFCs), were widely used as refrigerants, propellants, and solvents. However, due to environmental concerns, particularly their role in ozone depletion and their greenhouse gas potential, the production and use of many perhaloalkanes have been significantly restricted or phased out under international agreements. Some perhaloalkanes still find specialized applications in chemistry and industry.