siliconaluminumoxide

Siliconaluminumoxide is a descriptive term for oxide materials that contain silicon and aluminum in combination with oxygen. It is not a single defined compound; rather, it covers a class of aluminosilicate oxides with varying SiO2 to Al2O3 ratios that are used in ceramics and refractories. A prominent member of this family is mullite, with the empirical formula 3Al2O3·2SiO2, which crystallizes in the orthorhombic system and is valued for high-temperature stability and low thermal expansion.

In these materials, silicon and aluminum occupy different coordination sites within a three-dimensional oxide network, allowing for solid-solution variations and phase development depending on synthesis conditions. Typical properties include very high melting points, resistance to thermal shock, good hardness, and chemical inertness. The exact properties depend on composition and microstructure.

Production and processing: Siliconaluminumoxide materials are prepared by high-temperature solid-state reactions of alumina and silica mixtures, by sol–gel routes followed by firing, or by other ceramic-processing methods. They are used as refractory ceramics, ceramic coatings, catalyst supports, and components in advanced ceramics.

Safety: Fine powders may pose inhalation hazards and should be handled with appropriate protective equipment following standard industrial hygiene practices. As with other refractory oxides, contact with skin and eyes should be minimized.

See also: mullite, aluminosilicate, silica-alumina, refractory ceramic.