selfhardening

Selfhardening refers to a process where a material gains strength and rigidity over time without the addition of external curing agents or the application of significant heat or pressure. This phenomenon is most commonly observed in certain types of polymers and composites. The hardening occurs due to chemical reactions or physical changes within the material itself, initiated by exposure to ambient conditions like air, moisture, or even just time.

One common example is found in silicone sealants. Upon exposure to atmospheric moisture, these materials undergo a chemical cross-linking reaction, transforming from a liquid or paste to a solid, flexible rubber. Another instance is seen in some unsaturated polyester resins, which can cure through a free-radical polymerization process when exposed to air, although catalysts are often used to accelerate this reaction.

The rate and extent of selfhardening depend on various factors, including the specific chemical composition of the material, ambient temperature, humidity levels, and exposure to ultraviolet light. While selfhardening can be a convenient and energy-efficient method for achieving a solid state, it also means that such materials may have a limited shelf life or require specific storage conditions to prevent premature hardening. Understanding the mechanisms and influencing factors of selfhardening is crucial for selecting and utilizing these materials effectively in applications ranging from adhesives and sealants to coatings and composite manufacturing.