fluorosulfate

Fluorosulfate refers to a chemical compound containing the fluorosulfate anion, SO3F-. This anion is characterized by a central sulfur atom bonded to three oxygen atoms and one fluorine atom. The fluorosulfate group is considered a pseudohalide due to its structural and chemical similarities to halide ions like chloride. It can exist as a salt with various cations, such as sodium fluorosulfate (NaSO3F) or potassium fluorosulfate (KSO3F).

Fluorosulfate compounds are typically white crystalline solids. Their solubility in water varies depending on the cation. Some fluorosulfates can be synthesized through reactions involving sulfur trioxide and alkali metal fluorides or by reacting sulfuryl halides with alkali metal sulfates.

The fluorosulfate anion is a relatively stable species, though it can undergo hydrolysis in aqueous solutions, particularly under acidic or basic conditions, to form sulfate and fluoride ions. In organic chemistry, fluorosulfate esters (SO3F-OR) can be formed, which are sometimes used as reactive intermediates or derivatizing agents. The study of fluorosulfates is part of inorganic chemistry, focusing on their synthesis, structure, and reactivity. They are not as common as their sulfate or sulfite counterparts but hold interest in specific chemical applications and research.