chlorosilaner

Chlorosilaner is not a standard term in chemistry. In practice, it is commonly encountered as a misspelling or variant of chlorosilane, a class of organosilicon compounds that contain silicon–chlorine bonds. The term broadly covers chlorosilanes with formulas such as RnSiCl(4−n) and simple silane derivatives like monochlorosilane (H3SiCl), dichlorosilane (H2SiCl2), trichlorosilane (HSiCl3), and tetrachlorosilane (SiCl4).

Chlorosilanes are typically colorless liquids or gases that hydrolyze readily in the presence of water to form hydrochloric acid and silicic or siloxane species. They are moisture-sensitive and can be reactive with air, requiring careful handling in inert atmospheres or dry conditions. The chemistry of chlorosilanes is central to many processes in silicone and organosilicon chemistry, including the preparation of siloxanes, polymers, surface modifications, and various silicon-containing intermediates.

Industrial production of chlorosilanes generally involves controlled chlorination of silicon-containing precursors, such as hydrogen silanes or silicon tetrachloride, to yield the desired chlorinated silicon compound. Their reactivity with moisture makes them useful as reagents and intermediates, but also requires appropriate containment, corrosion-resistant equipment, and proper ventilation.

Safety and handling considerations include their corrosive and irritant nature, potential generation of hydrogen chloride upon hydrolysis, and the need for protective equipment and storage in dry, inert environments. Environmental release of chlorosilanes can be hazardous, necessitating careful waste management and spill response.

See also: chlorosilanes, organosilicon chemistry, silicon chlorides.