Garnieriite
Garnieriite is a rare mineral with the chemical formula (Na,Ca)2Mn3+3(PO4)2(OH)3. It was first discovered in 1977 in the Garnierite mine in the French Alps, from which it derives its name. Garnieriite is a member of the whitlockite group of minerals, which are characterized by their phosphate structure. It typically forms as a secondary mineral in phosphate-rich environments, often associated with other manganese minerals such as rhodonite and braunite.
The mineral is known for its distinctive deep red to brown color, which is due to the