plastoquinone

Plastoquinone is a lipid-soluble, electron-transport molecule found in the chloroplasts of plants and algae, as well as in some bacteria. It plays a crucial role in the light-dependent reactions of photosynthesis, specifically within the thylakoid membranes of the chloroplasts. Structurally, plastoquinone is a quinone, a type of organic compound that contains two ketone groups adjacent to each other.

During the light-dependent reactions of photosynthesis, plastoquinone facilitates the transfer of electrons from Photosystem II (PSII) to the cytochrome b6f complex. This process is essential for the generation of a proton gradient across the thylakoid membrane, which ultimately drives the synthesis of ATP through ATP synthase. Additionally, plastoquinone is involved in the transfer of electrons to Photosystem I (PSI), where they are used to reduce NADP+ to NADPH, another vital energy carrier in the Calvin cycle.

Plastoquinone exists in two main forms: oxidized (plastoquinone, PQ) and reduced (plastoquinol, PQH2). The oxidized form accepts two electrons and two protons to become the reduced form, which then donates the electrons to the cytochrome b6f complex. This cycle of oxidation and reduction is central to the electron transport chain in photosynthesis.

The importance of plastoquinone extends beyond its role in electron transport. It also participates in the regulation of gene expression and the protection of the photosynthetic apparatus from oxidative stress. Deficiencies or mutations affecting plastoquinone can lead to impaired photosynthetic efficiency and various physiological disorders in plants.