Selfreactives

Selfreactives are a class of chemical compounds that are inherently unstable and can undergo spontaneous decomposition or reaction without external initiation. This instability arises from the presence of specific functional groups or structural features within the molecule that store a significant amount of energy. Upon reaching a certain threshold, often triggered by minor disturbances like heat, friction, or impact, this stored energy is released rapidly, leading to a reaction.

The nature of the reaction can vary widely, ranging from the release of heat and gas to detonation. Common examples of selfreactive functional groups include nitro groups, azides, peroxides, and diazo compounds. These groups often contain weak bonds or have an unfavorable arrangement of atoms that makes them prone to breaking apart. The decomposition process can be exothermic, meaning it releases heat, which can further accelerate the reaction in a self-sustaining cycle.

Due to their hazardous nature, selfreactives require careful handling, storage, and transportation. Their classification and regulation are subject to strict safety protocols in industrial and laboratory settings. Understanding the specific properties and sensitivities of each selfreactive compound is crucial for preventing accidents. Research into selfreactives often focuses on stabilizing them, finding safer alternatives, or developing methods for controlled decomposition.